POP!_OS apparently uses systemd-boot (not to be confused with systemd). It apparently adds a Windows entry automatically if Windows is installed on the same disk. When Windows is installed on a different disk, it looks like booting the windows boot manager EFI program is still possible with systemd-boot. The instructions given in that link are a bit vague, though.
This page has a different, simpler approach and more specific steps. Apparently you can just copy the Microsoft EFI folder to a specific directory in your Linux drive’s ESP partition. I’d be a little bit concerned about Windows not being able to update its EFI bootloader, but I also don’t know if Windows ever updates that. The page also has instructions on how to interact with the systemd-boot menu during boot.
You could also install grub yourself, but I can’t guarantee that’ll be easy. Mashing F2 might be the sanest solution, unless you plan on booting into Windows every day.
This is a text post, so the OP wrote text corresponding to the title. You should be able to see it at the top of the post. (Spoiler, OP is basically asking the community why NixOS is better, because they don’t quite understand the advantages of using NixOS.)